I am unable to see the templates or stationary documents listed from Apply Settings in the File menu or from the Windows menu.
Your ChemDraw folder is not in the same folder as your ChemDraw application. Place your ChemDraw application in the same folder as your ChemDraw folder, preferably in the CS Applications folder. If you want the ChemDraw application accessible from another location, create an alias. You can also place the ChemDraw folder in the System Folder:Preferences.